You can add people to your Contacts list so they’ll be just a click away. You can also remove them from Contacts later if you want to.
Note: Sign in to Outlook on the web using an Office 365 work or school account. For more details, see How to sign in to Outlook on the web.
Add a Skype friend as a contact
On the Outlook toolbar, in the upper right corner, click Skype .
In the Skype pane, click inside the search box next to the magnifying glass, and enter the name of the person you want to add.
When Skype returns the name of the person you want to add, click the name, and then click Add to contacts.
Remove a Skype friend as a contact
In the Skype contacts list, search for the contact you want to remove, right-click the search result, and then click Delete contact.