Note: Sign in to Outlook on the web using any Microsoft account, including email accounts ending in @outlook.com, @live.com, @hotmail.com or @msn.com — and Office 365 work or student accounts.
Add a Skype friend as a contact
On the Outlook navigation bar, in the upper right corner, click Skype .
In the Skype pane, click inside the search box next to the magnifying glass, and enter the name of the person you want to add.
Note: If Skype doesn't return the person's name, click Search Skype Directory.
When Skype returns the name of the person you want to add, click the name, and then click Add To Contacts.
Remove a Skype friend as a contact
In the Skype contacts list, search for the contact you want to delete, right click the search result, and click Delete contact.